Websites the Help

MacFixIt- Users helping users. Probably better than the Apple discussion fourms.

MacScripter- Good site that is all about Mac Automation and Applescript.

Mac OS X Hints- The best place to go when you are looking for tips and reminders on things you know the system can do, you just can't remember how to do them.

Also look at these great books from:

Peachpit Press

Robin Williams Cool Mac Apps: Twelve apps for enhanced creativity and productivity (3rd Edition)
The Little Mac Book, Snow Leopard Edition
Microsoft Office 2011 for Mac: Visual QuickStart Guide
Mac OS X 10.6 Snow Leopard: Peachpit Learning Series
Photoshop CS4, Volume 1: Visual QuickStart Guide
Non-Designer's Design Book, The (3rd Edition)